Hi Ghazey06 - welcome to the BC forum.
Not sure, but I was under the impression that Tobacco and Alcohol are the only goods from the EU to UK which are subject to C&E Duties. Rest of stuff, including internet purchases from the EU, just like normal shopping. But please do check it out.
Googled this: [url="http://www.hmrc.gov.uk/customs/post/buying.htm#2"]http://www.hmrc.gov.uk/customs/post/buying.htm#2[/url] - hope it will help.
Al